SOLUBLE ORGANIC DERIVATIVES OF ALUMINOSILICATES WITH AL2SI2O4 AND AL4SI2O6 FRAMEWORKS

被引：66

作者：

MONTERO, ML ^{[1
]}

USON, I ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 20期

关键词：

D O I：

10.1002/anie.199421031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ring or a cage containing metal and oxygen atoms is formed in the reaction of RSi(OH)3 with HA1‐iBu2, depending on the molar ratio used. The structural parameters of the cage compound 1 are very similar to those of the mineral gismondine. Compound 1 is soluble in organic solvents and may suitable for the synthesis of aluminosilicates, in particular zeolites, because of its good leaving groups. R = (2,6‐iPr2C6H3)N(SiMe3). (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2103 / 2104

页数：2

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