Excited singlet-singlet spectra of anthraceme, N,N-diethylaniline and their CT complex

被引:39
作者
Goldschmidt, Chmouel R. [1 ]
Ottolenghi, Michael [1 ]
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel
关键词
D O I
10.1016/0009-2614(70)87065-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A transient absorption is observed in anthracene (A)-N, N-diethylaniline ( D) solutions in toluene excited by the 3371 angstrom line of a nitrogen laser. The lifetime of the transient matches that of the fluorescence of the excited (D center dot A) charge transfer complex. The absorption is assigned to a transition from the fluorescent CT state to a higher CT singlet of the complex. Excited singlet-singlet absorptions are also observed fox the free anthracene and N, N-diethylaniline molecules.
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页码:570 / 572
页数:3
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