INTRAMOLECULAR ANODIC OLEFIN COUPLING REACTIONS - THE USE OF ALLYSILANES

被引：10

作者：

MOELLER, KD

HUDSON, CM

机构：

[1] Department of Chemistry, Washington University, St. Louis

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 21期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)79910-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of allylsilanes as directing groups in the intramolecular electrochemical coupling of electron rich olefins has been examined. The allylsilanes were shown to provide an effective means for controlling product selectivity, and led to the formation of five- and six-membered ring products in 59-84% isolated yields.

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页码：2307 / 2310

页数：4

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