SEARCHING FOR THE IONIZED ALKENE ALKANOL COMPLEXES [C2H-4+./HOCH3] AND [C2H-4+./HOCH2CH3]

被引：13

作者：

CAO, JR

GEORGE, M

HOLMES, JL

机构：

[1] Chemistry Department, University of Ottawa, Ottawa, Ontario

来源：

ORGANIC MASS SPECTROMETRY | 1991年 / 26卷 / 05期

关键词：

D O I：

10.1002/oms.1210260520

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Experiments on a variety of isomeric [C3H8O]+. and [C4H10O]+. ions have failed to produce direct evidence for the involvement of the complex ions [C2H4+./HOCH3] and [C2H4+./HOC2H5]. For the isomers studied, the rearrangements prior to their dissociation of lowest energy requirement (loss of H2O and C2H5., respectively) are proposed to involve distonic and ylid ions.

引用

页码：481 / 485

页数：5

共 24 条

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