SYNTHESIS AND STRUCTURE OF A NEW MICROPOROUS ANIONIC DERIVATIVE OF GEO2 - [GE18O38(OH4)]8-[(C2N2H10)2+]4.2H2O

被引:65
作者
JONES, RH
CHEN, JS
THOMAS, JM
GEORGE, A
HURSTHOUSE, MB
XU, RR
LI, SG
LU, YQ
YANG, GD
机构
[1] QUEEN MARY & WESTFIELD COLL, DEPT CHEM, LONDON E1 4NS, ENGLAND
[2] JILIN UNIV, DEPT CHEM, CHANGCHUN, PEOPLES R CHINA
关键词
D O I
10.1021/cm00022a012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preparation and characterization of a novel, crystalline, microporous germanium oxide in which Ge exhibits 4-, 5-, and 6-fold coordination are described; its framework structure contains two types of oval 10-membered-ring and one type of 8-membered-ring channels which intersect one another, the largest diameter of the oval framework windows being 5.2 angstrom.
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页码:808 / 812
页数:5
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