SYNTHESIS AND CHARACTERIZATION OF CATIONIC TRINUCLEAR BINAP-RU(II) COMPLEXES - CRYSTAL-STRUCTURE OF [RU3CL5((S)-BINAP)3]BF4

被引：22

作者：

MASHIMA, K ^{[1
]}

HINO, T ^{[1
]}

TAKAYA, H ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,KYOTO 606,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 26期

关键词：

BINAP; RU(II) COMPLEX; X-RAY STRUCTURE OF TRINUCLEAR RU(II) COMPLEX; ASYMMETRIC HYDROGENATION; HOMOGENEOUS CATALYSIS;

D O I：

10.1016/0040-4039(91)80700-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of cationic complexes [RuX((S)-binap)(arene)]X (X = Cl, Br; arene = benzene, p-cymene) in methanol at 60-degrees-C or UV irradiation of the solution at room temperature afforded monocationic trinculear complexes [Ru3X5((S)-binap)3]X in 40-62% yields, whose novel structures have been determined based on spectral data, conductivity, and an X-ray crystallographic study.

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页码：3101 / 3104

页数：4

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