ARYLENE-BRIDGED AND ALKYLENE-BRIDGED SILICONATES

被引：20

作者：

LOY, DA ^{[1
]}

SMALL, JH ^{[1
]}

SHEA, KJ ^{[1
]}

机构：

[1] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a083

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4'-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and triethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

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页码：1484 / 1488

页数：5

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