ultraviolet-visible spectrophotometry;
feature selection;
partial least squares;
D O I:
10.1039/an9952002787
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
A method for eliminating unnecessary wavelengths is applied with the goal of achieving improved prediction ability in multicomponent determinations by UV/VIS spectrophotometry with partial least squares (PLS), The feature selection method is based on the regression coefficients of the closed form of the PLS model, This method was evaluated with calibration data of different types, and with different criteria to choose the optimum number of factors, The results presented suggest that wavelength selection improves the prediction ability of PLS method.