PASSIVE AND ACTIVE-ROLE OF FLUORESCERS IN THE CHEMI-LUMINESCENCE OF TETRAMETHOXYDIOXETANE

被引：18

作者：

WILSON, T

机构：

[1] The Biological Laboratories, Harvard University, Cambridge, Massachusetts

来源：

PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1979年 / 30卷 / 01期

关键词：

D O I：

10.1111/j.1751-1097.1979.tb07132.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Abstract— Tests for the possible catalytic role of fluorescers in the chemiluminescent decomposition of dioxetanes are discussed and applied to the case of tetramethoxydioxetane. This dioxetane, which can undergo direct thermal decomposition yielding excited methyl carbonate with subsequent excitation of fluorescers (for example 9, 10‐dibromoanthracene. DBA), is shown to be sensitive also to catalysis by fluorescers such as rubrene. 9, 10‐diphenyl‐anthracene (DPA) and 9, IOdicyanoanthracene (DCNA). The possibility of a charge‐transfer mechanism of chemiluminescent catalysis is suggested. Copyright © 1979, Wiley Blackwell. All rights reserved

引用

收藏

页码：177 / 183

页数：7

相关论文

共 21 条

[1] MECHANISM OF DIRECT AND RUBRENE ENHANCED CHEMILUMINESCENCE DURING ALPHA-PEROXYLACTONE DECARBOXYLATION [J].

ADAM, W ;

SIMPSON, GA ;

YANY, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1974, 78 (25) :2559-2569

[2] MECHANISM OF RUBRENE-ENHANCED CHEMILUMINESCENCE OF ALPHA-PEROXYLACTONES [J].

ADAM, W ;

CUETO, O ;

YANY, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2587-2589

[3] METAL-ION CATALYZED DECOMPOSITION OF TETRAMETHYL-1,2-DIOXETANE IN METHANOL [J].

BARTLETT, PD ;

BAUMSTAR.AL ;

LANDIS, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (17) :5557-5558

[4]

BAUMSTARK AL, 1976, TETRAHEDRON LETT, P2397

[5] BIOLUMINESCENCE AND CHEMILUMINESCENCE [J].

HASTINGS, JW ;

WILSON, T .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1976, 23 (06) :461-473

[6] CHEMICALLY-INITIATED ELECTRON EXCHANGE LUMINESCENCE - NEW CHEMILUMINESCENT REACTION PATH FOR ORGANIC PEROXIDES [J].

KOO, J ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :6107-6109

[7] BIOLUMINESCENCE OF FIREFLY - KEY STEPS IN FORMATION OF ELECTRONICALLY EXCITED-STATE FOR MODEL SYSTEMS [J].

KOO, JY ;

SCHMIDT, SP ;

SCHUSTER, GB .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1978, 75 (01) :30-33

[8] CHEMILUMINESCENCE OF DIPHENOYL PEROXIDE - CHEMICALLY-INITIATED ELECTRON EXCHANGE LUMINESCENCE - NEW GENERAL MECHANISM FOR CHEMICAL PRODUCTION OF ELECTRONICALLY EXCITED-STATES [J].

KOO, JY ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) :4496-4503

[9] TETRAMETHYL-1,2-DIOXETANE - MECHANISM FOR AN AUTOCATALYTIC DECOMPOSITION - EVIDENCE FOR A QUANTUM CHAIN REACTION [J].

LECHTKEN, P ;

YEKTA, A ;

TURRO, NJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (09) :3027-3028

[10]

Lee D. C. S., 1973, CHEMILUMINESCENCE BI, P265