THE RHODIUM-CATALYZED HYDROBORATION OF OLEFINS - A MECHANISTIC INVESTIGATION

被引：80

作者：

EVANS, DA

FU, GC

机构：

[1] Department of Chemistry, Harvard University, Cambridge

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期

关键词：

D O I：

10.1021/jo00295a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Labeling studies carried out on the rhodium-catalyzed olefin hydroboration reaction reveal that the degree of reversibility of the elementary steps in the catalytic cycle is highly substrate dependent. The implications of these observations are discussed. © 1990, American Chemical Society. All rights reserved.

引用

页码：2280 / 2282

页数：3

共 20 条

[1] SUBSTRATE-CONTROLLED DIASTEREOSELECTIVITY IN CATALYZED AND UNCATALYZED HYDROBORATIONS OF ALLYLIC AMINE DERIVATIVES
BURGESS, K
OHLMEYER, MJ
[J]. TETRAHEDRON LETTERS, 1989, 30 (43) : 5857 - 5860
[2] DIASTEREOCONTROL IN RHODIUM-CATALYZED HYDROBORATION OF CHIRAL ACYCLIC ALLYLIC ALCOHOL DERIVATIVES
BURGESS, K
OHLMEYER, MJ
[J]. TETRAHEDRON LETTERS, 1989, 30 (04) : 395 - 398
[3] ON CATALYZED AND UNCATALYZED HYDROBORATIONS OF CHIRAL ALLYLIC ALCOHOLS AND AMINES
BURGESS, K
OHLMEYER, MJ
[J]. TETRAHEDRON LETTERS, 1989, 30 (43) : 5861 - 5864
[4] ENANTIOSELECTIVE HYDROBORATION MEDIATED BY HOMOCHIRAL RHODIUM CATALYSTS
BURGESS, K
OHLMEYER, MJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (21) : 5178 - 5179
[5] MODELING CHEMICAL-REACTIVITY .7. THE EFFECT OF A CHANGE IN RATE-LIMITING STEP ON THE STEREOSELECTIVITY OF ELECTROPHILIC ADDITION TO ALLYLIC ALCOHOLS AND RELATED CHIRAL ALKENES
CHAMBERLIN, AR
MULHOLLAND, RL
KAHN, SD
HEHRE, WJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) : 672 - 677
[6] COLLMAN JP, 1987, PRINCIPLES APPLICATI
[7] HYDROFORMYLATION OF TRICARBONYL(ETA-6-STYRENE)CHROMIUM AND RELATED-COMPOUNDS
DOYLE, MM
JACKSON, WR
PERLMUTTER, P
[J]. TETRAHEDRON LETTERS, 1989, 30 (39) : 5357 - 5360
[8] RHODIUM(I)-CATALYZED HYDROBORATION OF OLEFINS - THE DOCUMENTATION OF REGIOCHEMICAL AND STEREOCHEMICAL CONTROL IN CYCLIC AND ACYCLIC SYSTEMS
EVANS, DA
FU, GC
HOVEYDA, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) : 6917 - 6918
[9] MECHANISM AND STEREOSELECTIVITY OF ASYMMETRIC HYDROGENATION
HALPERN, J
[J]. SCIENCE, 1982, 217 (4558) : 401 - 407
[10] CATALYTIC ASYMMETRIC HYDROBORATION OF STYRENES
HAYASHI, T
MATSUMOTO, Y
ITO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) : 3426 - 3428

← 1 2 →