ELECTROCHEMISTRY OF ZEOLITE-ENCAPSULATED COBALT SALEN COMPLEXES IN ACETONITRILE AND DIMETHYL-SULFOXIDE SOLUTIONS

被引：67

作者：

BEDIOUI, F ^{[1
]}

DEBOYSSON, E ^{[1
]}

DEVYNCK, J ^{[1
]}

BALKUS, KJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,RICHARDSON,TX 75083

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 24期

关键词：

D O I：

10.1039/ft9918703831

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Co(II) complexes of N,N'-bis (salicylaldehyde)ethylenediimine (salen) have been entrapped in the supercages of zeolite Y. The redox properties of these complexes are investigated by cyclic voltammetry. The results show the existence of two different kind of entrapped Co(III) salen forms within the zeolite. The accessibility and redox activity of the intrazeolite complexes are discussed.

引用

页码：3831 / 3834

页数：4

共 17 条

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