HALOGEN-EXCHANGE REACTIONS BETWEEN ALKYL FLUORIDES AND BORON TRIHALIDES OR TITANIUM TETRAHALIDES - A CONVENIENT SYNTHESIS OF ALKYL-HALIDES FROM ALKYL FLUORIDES

被引：18

作者：

NAMAVARI, M

SATYAMURTHY, N

BARRIO, JR

机构：

[1] UNIV CALIF LOS ANGELES,SCH MED,DEPT MOLEC & MED PHARMACOL,LOS ANGELES,CA 90024

[2] UNIV CALIF LOS ANGELES,SCH MED,STRUCT BIOL & MOLEC MED LAB,LOS ANGELES,CA 90024

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 01期

基金：

美国国家卫生研究院;

关键词：

HALOGEN-EXCHANGE REACTIONS; ALKYL FLUORIDES; BORON TRIHALIDES; TITANIUM TETRAHALIDES; NMR SPECTROSCOPY; MASS SPECTROMETRY;

D O I：

10.1016/0022-1139(94)03193-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple and effective method for converting fluoroalkanes to their corresponding chloro-, bromo- and iodo-alkanes using commercially available boron trihalides and titanium tetrahalides is described.

引用

页码：89 / 93

页数：5

共 26 条

[1] ADDITION COMPOUNDS OF GALLIUM TRICHLORIDE WITH METHYL HALIDES [J].

BROWN, HC ;

EDDY, LP ;

WONG, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (24) :6275-6278

[2] BORON HALIDES AS REAGENTS IN INORGANIC SYNTHESES .3. PREPARATION AND CHARACTERIZATION OF HALOGEN-BRIDGED AND PSEUDOHALOGEN-BRIDGED, BINUCLEAR, CATIONIC COMPLEXES OF PLATINUM(II) [J].

DRUCE, PM ;

LAPPERT, MF ;

RILEY, PNK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (03) :438-&

[3] BORON HALIDES AS REAGENTS IN INORGANIC SYNTHESES .2. FURTHER GENERAL METHOD FOR PREPARATION OF ANHYDROUS BROMIDES AND IODIDES - HALOGEN EXCHANGE REACTIONS [J].

DRUCE, PM ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (22) :3595-&

[4]

DRUCE PM, 1967, J CHEM SOC CHEM COMM, P486

[5] KINETICS OF HALOGEN-EXCHANGE REACTION BETWEEN ALKYL-HALIDES (RY) AND BORON TRIHALIDES (BX3) - EVIDENCE FOR FORMATION OF ADDUCTS RY, BX3 [J].

GOLDSTEIN, M ;

HEMMINGS, JA ;

HAINES, LIB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (20) :2260-+

[6]

HOOPER DL, 1967, J MOL SPECTOSC, V24, P227

[7] PROTON-TRANSFER REACTIONS .2. EFFECTS OF INTERNAL RETURN ON REACTIVITY DIFFERENCE BETWEEN ALKOXIDE-PROMOTED ELIMINATIONS IN TERT-BUTYL ALCOHOL AND ETHYL-ALCOHOL [J].

KOCH, HF ;

TUMAS, W ;

KNOLL, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5423-5429

[8]

LANCELOT EJ, 1972, CARBONIUM IONS, V3, pCH27

[9] DIRECTIVE EFFECTS IN BENZYLIC HYDROGEN-ATOM ABSTRACTION .6. HALOGENATION OF ARETHYL FLUORIDES [J].

LEE, KH ;

LOKE, SE ;

YEOH, GH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (01) :10-12

[10] REDISTRIBUTION AND EXCHANGE REACTIONS IN GROUPS 2B-7B [J].

LOCKHART, JC .

CHEMICAL REVIEWS, 1965, 65 (01) :131-&

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