VIBRATIONAL SPECTRA OF HEXACHLOROURANATE AND HEXACHLOROTHORATE IONS - UCL62- AND THCL62-

被引：20

作者：

WOODWARD, LA

WARE, MJ

机构：

[1] Inorganic Chemistry Laboratory, Oxford University

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 07期

关键词：

D O I：

10.1016/0584-8539(68)80191-6

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Raman and infra-red spectra of UCl2-6 and ThCl2-6 have been obtained from methyl cyanide solutions of their alkylammonium or alkylphosphonium salts. The fundamentals are assigned in terms of the molecular point group O h and their relation to vibrational progressions in the ultra-violet spectra is discussed. A force constant calculation indicates that UCl2-6 and ThCl2-6 have MCl bonds significantly stronger than those of PbCl2-6. The influence on the vibrational spectra of the incomplete {cauchy integral}-shell in UCl2-6 is also noted and discussed. © 1968.

引用

页码：921 / &

共 19 条

[1] FAR-INFRA-RED ABSORPTION SPECTRA OF SOME COMPLEX HALIDES OF MOLYBDENUM AND TUNGSTEN [J].