STUDIES IN THE CHEMISTRY OF POLYVALENT ORGANOIODINE COMPOUNDS .5. THE CYCLIC STRUCTURE OF 2-IODOSYL-BENZOIC AND 2-IODYL-BENZOIC ACID ANIONS - A BASICITY AND X-RAY CRYSTALLOGRAPHIC STUDY

被引：37

作者：

KATRITZKY, AR ^{[1
]}

SAVAGE, GP ^{[1
]}

PALENIK, GJ ^{[1
]}

QIAN, K ^{[1
]}

ZHANG, ZY ^{[1
]}

DURST, HD ^{[1
]}

机构：

[1] USA,CTR CHEM RES DEV & ENGN,RES DIRECTORATE,DIV CHEM,APPL CHEM BRANCH,ABERDEEN PROVING GROUND,MD 21010

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1990年 / 10期

关键词：

D O I：

10.1039/p29900001657

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The crystal structures of sodium 2-iodosyl-4-nitrobenzoate and sodium 2-iodyl-4-nitrobenzoate demonstrate a bicyclic structure for each. pK a considerations indicate that the anions remain cyclized in solution. The crystal structure of 2-iodyl-5-methylbenzoic acid has also been obtained.

引用

页码：1657 / 1661

页数：5

共 27 条

[1] SECONDARY BONDING .6. DISTORTED OCTAHEDRAL GEOMETRY IN SELENINYL DICHLORIDE-DIOXAN (1-1) AND IODYLBENZENE [J].