ASYMMETRIC DIELS-ALDER REACTIONS OF A CHIRAL SUGAR NITROALKENE - DIASTEREOFACIAL SELECTIVITY AND REGIOSELECTIVITY

被引：14

作者：

SERRANO, JA ^{[1
]}

CACERES, LE ^{[1
]}

ROMAN, E ^{[1
]}

机构：

[1] UNIV EXTREMADURA,FAC CIENCIAS,DEPT QUIM ORGAN,E-06071 BADAJOZ,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 08期

关键词：

D O I：

10.1039/p19920000941

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The uncatalysed Diels-Alder addition of 1-(trimethylsilyloxy)- and 1-acetoxybuta-1,3-diene to a sugar-derived nitroalkene proceeds with complete regioselectivity and diastereofacial selectivity to yield crystalline, optically pure, cyclohexene derivatives.

引用

页码：941 / 942

页数：2

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