RING-CLOSURE OF HALOGENONAPHTHOQUINONES WITH POTASSIUM 2-AMINOBENZENETHIOLATE - TAUTOMERISM AND SUBSTITUENT EFFECTS

被引:10
作者
TAKAGI, K [1 ]
KANAMOTO, S [1 ]
ITOH, K [1 ]
MATSUOKA, M [1 ]
KIM, SH [1 ]
KITAO, T [1 ]
机构
[1] UNIV OSAKA PREFECTURE,COLL ENGN,DEPT APPL CHEM,SAKAI,OSAKA 591,JAPAN
关键词
LASERS; DYE - Applications - NUCLEAR MAGNETIC RESONANCE - OPTICAL DEVICES - Applications;
D O I
10.1016/0143-7208(87)85007-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Ring-closure of halogenonaphthoquinones by reaction with potassium 2-aminobenzenethiolate gave a series of naphthoquinoid infrared dyes which were useful as optical information recording media for semiconductor lasers. The ring-closure reaction was influenced mainly by the ring-substituents, by the quinone-quinoneimine tautomerism of the intermediates and also by the reaction conditions. Some of the tautomers were isolated and tautomerism in solution was also observed.
引用
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页码:71 / 82
页数:12
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