STUDY OF THE EFFECT OF SURFACTANTS ON ELECTRODE PROCESSES IN MOLTEN-SALTS

被引：12

作者：

DELIMARSKY, YK

TUMANOVA, NK

机构：

[1] Institute of General and Inorganic Chemistry, Ukrainian SSR Academy of Sciences, Kiev

来源：

ELECTROCHIMICA ACTA | 1979年 / 24卷 / 01期

关键词：

D O I：

10.1016/0013-4686(79)80034-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of various organic substances on cathodic processes in the K,Na{divides}SCN, K,Li{divides}NO3, 2Al,Na{divides}Cl and K,Na,Li,Cs{divides}Cl melts has been studied by ac polarography, spectroscopic and potentiometric methods as well as by surface tension and differential capacity measurements. It has been shown that adsorption of organic substances on Pt electrodes takes place in the melts at temperatures up to 300°C and that the substances studied should be regarded as surfactants. Some surfactants were used for obtaining aluminium electrodeposits with given properties from the 2Al,Na{divides}Cl melt. © 1979.

引用

页码：19 / 24

页数：6

共 10 条

[1]

Damaskin B.B., 1968, ADSORBTSIYA ORGANICH

[2]

DELIMARSKII YK, 1970, ELECTROKHIMIYA, V6, P556

[3]

DELIMARSKIJ JK, 1969, ELEKTROKHIMIYA, V5, P145

[4]

DELIMARSKY YK, 1960, ELEKTRODNYE PROTESES

[5]

GEYROVSKY Y, 1965, OSNOVY POLAROGRAFII

[6]

GRAFOV BM, 1973, ELEKTROKHIMICHESKIYE

[7]

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[8]

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[9]

SEMENCHENKO VK, 1947, ZH FIZ KHIM+, V21, P613

[10]

SOKOLOV NM, 1969, ZH NEORGAN KHIMII, V14, P286

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