UNACTIVATED 2-AZA-1,3-DIENES - HALOGENATION AND FACE SELECTIVITY IN DIELS-ALDER REACTIONS

被引：9

作者：

BARLUENGA, J

GONZALEZ, FJ

FUSTERO, S

机构：

[1] Departamento de Química Organometálica, Facultad de Química, Universidad de Oviedo

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)94564-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of monohalogenated 2-aza-l,3-dienes 2 is described.The first example of face selectivity in Diels-Alder reactions of dienes 2 with diethyl azodiearboxylate and benzaldehyde is also reported. © 1990.

引用

页码：397 / 398

页数：2

共 6 条

[1] A SIMPLE REGIOSPECIFIC SYNTHESIS OF SUBSTITUTED PYRIDINES FROM 2-AZA 1,3-DIENES [J].

BARLUENGA, J ;

JOGLAR, J ;

GONZALEZ, FJ ;

GOTOR, V ;

FUSTERO, S .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (25) :5960-5963

[2]

BARLUENGA J, 1988, B SOC CHIM BELG, V97, P545

[3] DIELS-ALDER REACTIONS OF AZADIENES [J].

BOGER, DL .

TETRAHEDRON, 1983, 39 (18) :2869-2939

[4]

BOGER DL, 1987, HETERODIELSALDER MET, P101

[5] REACTIVITY OF BETA-HALOENAMINES - A REVIEW [J].

DEKIMPE, N ;

SCHAMP, N .

ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1983, 15 (1-2) :71-135

[6] FACE SELECTIVITY IN DIELS-ALDER REACTIONS OF CHIRAL DIENES CONTAINING ALLYLIC SUBSTITUENTS [J].

FISHER, MJ ;

HEHRE, WJ ;

KAHN, SD ;

OVERMAN, LE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) :4625-4633

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