(ME3SI)3SISH - A NEW RADICAL-BASED REDUCING AGENT

被引：33

作者：

BALLESTRI, M ^{[1
]}

CHATGILIALOGLU, C ^{[1
]}

SECONI, G ^{[1
]}

机构：

[1] CNR,ICOCEA,I-40064 OZZANO EMILIA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 408卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)80107-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(trimethylsilyl)silanethiol is an effective and useful reducing agent for some organic substrates. The reduction involves free-radical chain reactions.

引用

页码：C1 / C4

页数：4

共 21 条

[1] ADDITION OF TRIS(TRIMETHYLSILYL)SILYL RADICALS TO THE CARBONYL GROUP [J].

ALBERTI, A ;

CHATGILIALOGLU, C .

TETRAHEDRON, 1990, 46 (11) :3963-3972

[2] THIOLS AS POLARITY REVERSAL CATALYSTS FOR HYDROGEN-ATOM TRANSFER FROM ORGANOSILANES TO ALKYL RADICALS - REDUCTION OF ALKYL-HALIDES BY TRIETHYLSILANE [J].

ALLEN, RP ;

ROBERTS, BP ;

WILLIS, CR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (18) :1387-1388

[3] TRIS(TRIMETHYLSILYL)SILANE AS A RADICAL-BASED REDUCING AGENT IN SYNTHESIS [J].

BALLESTRI, M ;

CHATGILIALOGLU, C ;

CLARK, KB ;

GRILLER, D ;

GIESE, B ;

KOPPING, B .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) :678-683

[4] ABSOLUTE RATE CONSTANTS FOR THE ADDITION OF TRIETHYLSILYL RADICALS TO THE CARBONYL GROUP [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) :5119-5123

[5] ABSOLUTE RATE CONSTANTS FOR THE REACTION OF TRIETHYLSILYL RADICALS WITH RING-SUBSTITUTED BENZYL CHLORIDES [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (05) :938-940

[6] ALKYL ISOCYANIDES AS PRECURSORS FOR THE FORMATION OF CARBON-CARBON BONDS [J].

CHATGILIALOGLU, C ;

GIESE, B ;

KOPPING, B .

TETRAHEDRON LETTERS, 1990, 31 (42) :6013-6016

[7] ABSOLUTE RATE CONSTANTS FOR THE ADDITION OF TRIETHYLSILYL RADICALS TO VARIOUS UNSATURATED-COMPOUNDS [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (10) :3292-3296

[8]

CHATGILIALOGLU C, 1990, SYNLETT, P219

[9] ABSOLUTE RATE CONSTANTS FOR THE REACTION OF TRIETHYLSILYL RADICALS WITH ORGANIC HALIDES [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) :5123-5127

[10] TRIS(TRIMETHYLSILYL)SILANE - A NEW REDUCING AGENT [J].

CHATGILIALOGLU, C ;

GRILLER, D ;

LESAGE, M .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) :3641-3642

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