Low Magnetic Field DNP of Diamagnetic Products Formed in Reactions Accompanied by Electron Hopping

被引：9

作者：

Bagryanskaya, E. G. ^{[1
]}

Lukzen, N. N. ^{[1
]}

Koptyug, I. V. ^{[1
]}

Sagdeev, R. Z. ^{[1
]}

Usacheva, M. N. ^{[2
]}

机构：

[1] Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia

[2] Ukrainian Acad Sci, Inst Phys Chem, Kiev, Ukraine

来源：

APPLIED MAGNETIC RESONANCE | 1990年 / 1卷 / 03期

关键词：

D O I：

10.1007/BF03166024

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

DNP generation at diamagnetic products of electron transfer reactions accompanied by electron hopping in low magnetic fields has been investigated both experimentally and theoretically. A comparison of experimental and calculated DNP dependencies on reactant concentration and mw-field magnitude was made. The electron hopping rate constant for dimethylaniline radical-cation was evaluated. The value obtained corresponds to those reported in literature.

引用

页码：431 / 443

页数：13

共 21 条

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