REACTION OF 1,2-DEHYDRO-O-CARBORANE WITH ACETYLENES - ENE REACTIONS AND CYCLOADDITION TO GIVE AN ANALOG OF BENZOCYCLOBUTADIENE

被引:44
作者
CUNNINGHAM, RJ [1 ]
BIAN, NY [1 ]
JONES, M [1 ]
机构
[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544
关键词
D O I
10.1021/ic00100a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of 1,2-dehydro-o-carborane with methylphenylacetylene leads to the first carborane fused to an unsaturated four-membered ring. This compound is much more stable than the conceptually related benzocyclobutadienes.
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页码:4811 / 4812
页数:2
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