ALLYLSILANES IN ORGANIC-SYNTHESIS - CONVENIENT PREPARATION OF SYNTHETIC INTERMEDIATES BY CATALYTIC HYDROSILATION OF ACETYLENIC ALCOHOLS

被引:54
作者
MURPHY, PJ [1 ]
SPENCER, JL [1 ]
PROCTER, G [1 ]
机构
[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)94428-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Synthetically useful vinylslane-alcohols such as (1) can be easily prepared by the catalytic hydrosilation of the appropriate acetylenic alcohols in high yield, and with excellent regioand stereoselectivity, without the need to protect the hydroxyl group. © 1990.
引用
收藏
页码:1051 / 1054
页数:4
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