BAEYER-VILLIGER OXIDATION OF BICYCLIC KETONES BY CYLINDROCARPON-DESTRUCTANS ATCC-11011

被引：17

作者：

KONIGSBERGER, K

BRAUNEGG, G

FABER, K

GRIENGL, H

机构：

[1] GRAZ UNIV TECHNOL,INST ORGAN CHEM,A-8010 GRAZ,AUSTRIA

[2] GRAZ UNIV TECHNOL,CHRISTIAN DOPPLER LAB CHIRAL CPDS,A-8010 GRAZ,AUSTRIA

[3] GRAZ UNIV TECHNOL,INST BIOTECHNOL,A-8010 GRAZ,AUSTRIA

来源：

BIOTECHNOLOGY LETTERS | 1990年 / 12卷 / 07期

关键词：

D O I：

10.1007/BF01086344

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Baeyer-Villiger oxidation of bicyclic ketones 1a, 1b and 4 using whole cell suspensions of the fungus Cylindrocarpon destructans was found to proceed quantitatively and in case of substrate (±)-1b a moderate enantioselectivity was observed leading to (1 S,6 R)-1b and (1 R,6 S)-2b with 28% and 27% e.e., respectively. © 1990 Kluwer Academic Publishers.

引用

页码：509 / 514

页数：6

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