OUTER-SHELL-REORGANIZATION ENERGY FOR ELECTRON-TRANSFER REACTIONS IN REVERSE MICELLES

被引：3

作者：

DILONARDO, M ^{[1
]}

MAESTRO, M ^{[1
]}

机构：

[1] CNR,CTR STUDIO CHIM PLASMI,I-70126 BARI,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 04期

关键词：

D O I：

10.1016/0009-2614(91)90333-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron-transfer reactions taking place in a bulk medium have been widely studied with respect to the influence of the medium on the reaction rate. We deal with the same type of reaction occurring in a finite-sized medium, simulating a reverse micelle. We show how the Marcus classical formulae must be modified to take into account the finite size of the medium, and present some relevant calculations which are illustrative of the effects of this finiteness in different cases.

引用

页码：353 / 357

页数：5

共 18 条

[1]

BELONOGOVA O V, 1983, Biokhimiya, V48, P379

[2]

BUHKS E, 1984, INORG CHEM, V88, P325

[3]

Fletcher P. D. I., 1984, REVERSE MICELLES, P73

[4] OUTER SPHERE ENERGY OF REORGANIZATION IN CHARGE-TRANSFER PROCESSES [J].