PHASE-EQUILIBRIA IN THE SYSTEM AL4C3-BE2C-SIC

被引:23
作者
SCHNEIDER, G
GAUCKLER, LJ
PETZOW, G
ZANGVIL, A
机构
[1] Max Planck Institut fuer Metallforschung, Institut fuer Werkstoffwischenschaften, Pulvermetallurgisches Laboratorium, Stuttgart
关键词
D O I
10.1111/j.1151-2916.1979.tb12734.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The 1860°C isothermal section of the system Al4C3‐Be2C‐SiC was investigated on hot‐pressed samples. The equilibrium relations involve previously known phases SiC, Be2C, A14C3, Al,SiC4, and seven newly found compounds. On the binary Al4C3‐Be2C, three phases with molar ratios 3:1, 1:1, and 1:3 occur with large homogeneity ranges and deviations of stoichiometry. In the ternary, four phases with molar ratios Al4C3:Be2C:SiC of 4:1:1, 4:2:1, 4:2:2, and 8:1:4 occur. All newly found compounds show hexagonal symmetry with a∼0.33 nm and c ranging from 1.65 to 5.45 nm, except Al4C3=3Be2C, which is cubic with a= 0.4611 nm. Copyright © 1979, Wiley Blackwell. All rights reserved
引用
收藏
页码:574 / 576
页数:3
相关论文
共 6 条
[1]  
[Anonymous], 1966, ACTA CRYSTALLOGR 4
[2]   OPTICAL AND X-RAY POWDER DIFFRACTION DATA FOR AL4SIC4 [J].
BARCZAK, VJ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1961, 44 (06) :299-299
[3]  
MATYUSHENKO NN, 1966, POROSHK METALL, P61
[4]   A REVIEW OF STRUCTURE OF SILICON CARBIDE [J].
SHAFFER, PTB .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :477-&
[5]  
STACKELBERG MV, 1934, Z PHYS CHEM, V27, P37
[6]  
ZANGVIL A, UNPUBLISHED