COMPLEXES OF NICKEL(2), COBALT(2), AND SILVER(I) WITH 2-, 3-, AND 4-CYANOPYRIDINE N-OXIDES

被引：18

作者：

NATHAN, LC

NELSON, JH

RICH, GL

RAGSDALE, RO

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 07期

关键词：

D O I：

10.1021/ic50077a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordinating properties of 2-, 3-, and 4-cyanopyridine N-oxides have been investigated. With cobalt(II) and nickel(II) all three N-oxides coordinate through the oxygen, giving hexacoordinate complexes in each case. For silver (I), 4-cyanopyridine N-oxide coordinates through the oxygen, while 2-cyanopyridine N-oxide appears either to contain bridging N-oxide groups coordinated through the oxygen or to involve coordination through both the N-oxide oxygen and the nitrile group. The silver complexes have the AgClO4.2L stoichiometry. © 1969, American Chemical Society. All rights reserved.

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页码：1494 / &

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