THE ADDITION OF HALOGENOCARBONS TO ALKENES IN THE PRESENCE OF [FE2(CO)4(ETA-C5H5)2] AND RELATED COMPLEXES

被引：34

作者：

DAVIS, R ^{[1
]}

DURRANT, JLA ^{[1
]}

KHAZAL, NMS ^{[1
]}

BITTERWOLF, TE ^{[1
]}

机构：

[1] USN ACAD,DEPT CHEM,ANNAPOLIS,MD 21402

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85248-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A kinetic study has been made of the addition of halogenocarbons to alkenes in the presence of [Fe2(CO)4(η-C5H5)2] (I). The results, together with the results of cross-over addition reactions of a halogenocarbon mixture and cross-over studies on catalyst mixtures of I and [Fe2(CO)4(η-C5Me5)2] (II) have been interpreted in terms of a mechanism which involves catalysis by an intact dinuclear species, probably [Fe2(CO)3(η-C5R5)2], but which also involves free radical intermediates. © 1990.

引用

页码：229 / 239

页数：11

共 14 条

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