THE USE OF OZONATION TO REDUCE THE POTENTIAL FOR FORMING TRIHALOMETHANE COMPOUNDS IN CHLORINATING RESORCINOL, PHLOROGLUCINOL AND 1,3 CYCLOHEXANEDIONE

This study concerns the ozonation of Resorcinol, Phloroglucinol and 1,3 Cyclohexanedione in the presence of bromide ion in a bubble column, prior to chlorination. Preozonation in aqueous solutions reduces the potential for forming chlorinated trihalomethane compounds. At organic concentrations greater than 10–4 M a short ozonation time increases the potential for forming trihalo-compounds. At longer ozonation times the reverse is true. Finally the influence of mass transfer and chemical reaction on the ozone absorption rate have been evaluated following the film theory. © 1990, Taylor & Francis Group, LLC. All rights reserved.