EFFECT OF WATER ON THE MECHANISM OF HYDROGENATIONS CATALYZED BY RHODIUM PHOSPHINE COMPLEXES

被引：34

作者：

JOO, F

CSIBA, P

BENYEI, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 21期

关键词：

D O I：

10.1039/c39930001602

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the action of H-2 in aqueous solutions, the water soluble analogue of Wilkinson's catalyst, [RhCl(tppms)3] [tppms=P(C6H5)2(C6H4SO3Na)], gives [RhH(tppms)3] instead of [RhH2Cl(tppms)3] and this is reflected in the rates and selectivities of hydrogenations using this catalyst.

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页码：1602 / 1604

页数：3

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