RAMAN SCATTERING AS A PROBE OF PURE-CRYSTAL PHONONS IN TL+-DOPED POTASSIUM HALIDES

被引:40
作者
HARLEY, RT
PAGE, JB
WALKER, CT
机构
[1] Department of Physics, Northwestern University, Evanston
[2] Department of Physics, Cornell University, Ithaca
[3] Department of Physics, Arizona State University, Tempe, AZ
关键词
D O I
10.1103/PhysRevLett.23.922
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Raman scattering data are reported for Tl+ impurities in KCl, KBr, and KI. Strong lines of Eg symmetry and weaker lines of A1g, Eg, and T2g symmetry are observed. Theoretical calculations based on breathing-shell-model phonons, with no impurity-induced change in force constants, are seen to be in agreement with the data. It appears that Tl+ acts as an isotopic impurity and allows one to use the Raman effect as a direct probe of the pure-crystal phonons. © 1969 The American Physical Society.
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页码:922 / &
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