PALLADIUM-CATALYZED VINYLATION OF CONJUGATED DIENES

被引：34

作者：

PATEL, BA ^{[1
]}

KAO, LC ^{[1
]}

CORTESE, NA ^{[1
]}

MINKIEWICZ, JV ^{[1
]}

HECK, RF ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19711

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 06期

关键词：

D O I：

10.1021/jo01320a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tertiary 2, 5-dienylamines are produced in moderate to good yields when vinylic halides are reacted with conjugated dienes and morpholine or piperidine in the presence of palladium catalysts. The vinylic group always adds to the terminal position of the least-substituted double bond of the diene system. The amine products are easily converted into allylic chlorides by reaction with chloroformate esters. © 1979, American Chemical Society. All rights reserved.

引用

页码：918 / 921

页数：4

共 8 条

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