CYCLOPENTADIENYLCYCLOOCTATETRAENETITANIUM

被引：56

作者：

VANOVEN, HO

MEIJER, HJD

机构：

[1] Laboratorium voor Anorganische Chemie, Rijksuniversiteit, Groningen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 19卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)85309-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex C5H5TiC8H8 was prepared by reaction of K2C8H8 with either C5H5TiCl3, (C5H5)2, or a mixture of TiCl4 and C5H5Na in tetrahydrofuran or toluene. The new compound is thermally stable, but it is sensitive to oxygen. There is one unpaired electron per molecule. The infrared spectrum shows the C5H5 group and probably also the C8H8 group to be π-bonded to the metal. The mass spectrum has been studied and a partial fragmentation scheme is given. © 1969.

引用

页码：373 / &

共 8 条

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