KINETICS, PRODUCTS, AND MECHANISMS OF REACTION OF TERT-BUTYL CHLORIDE WITH SODIUM METHOXIDE IN METHANOL AND DIMETHYL-SULFOXIDE METHANOL SOLVENTS

被引：6

作者：

BUNNETT, JF

MIGDAL, CA

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1989年 / 54卷 / 13期

关键词：

D O I：

10.1021/jo00274a014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：3037 / 3041

页数：5

共 22 条

[1] SOLVATION OF IONS .14. PROTIC-DIPOLAR APROTIC SOLVENT EFFECTS ON RATES OF BIMOLECULAR REACTIONS SOLVENT ACTIVITY COEFFICIENTS OF REACTANTS AND TRANSITION STATES AT 25 DEGREES [J].

ALEXANDE.R ;

KO, ECF ;

PARKER, AJ ;

BROXTON, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (19) :5049-&

[2] DEUTERIUM-PROTIUM FRACTIONATION IN SOLUTIONS OF METHOXIDE ION IN MIXTURES OF METHANOL AND DIMETHYLSULFOXIDE [J].

BALTZER, L ;

BERGMAN, NA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1982, (03) :313-319

[3] SOLVOLYSIS OF SOME TRIMETHYLNORBORNYL CHLORIDES [J].

BELTRAME, P ;

BUNTON, CA ;

DUNLOP, A ;

WHITTAKER, D .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (FEB) :658-+

[4] MECHANISM OF SUBSTITUTION AT A SATURATED CARBON ATOM .34. KINETIC EFFECTS OF HYDROXIDE AND ALKOXIDE IONS ON THE RATE-CONTROLLING AND PRODUCT-FORMING STAGES OF UNIMOLECULAR SOLVOLYSIS OF TERT-BUTYL AND DIPHENYLMETHYL HALIDES [J].

BENFEY, OT ;

HUGHES, ED ;

INGOLD, CK .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (JUL) :2494-2498

[5] KINETICS OF METHANOLYSIS OF T-BUTYL CHLORIDE, BROMIDE, AND IODIDE [J].

BIORDI, J ;

MOELWYNHUGHES, EA .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (NOV) :4291-&

[6]

BLANDAMER MJ, 1977, ADV PHYS ORG CHEM, V14, P331

[7] ACIDITY FUNCTIONS FOR STRONGLY BASIC SOLUTIONS [J].

BOWDEN, K .

CHEMICAL REVIEWS, 1966, 66 (02) :119-&

[8] ELIMINATION REACTIONS OF BENZYLDIMETHYLCARBINYL CHLORIDE - E2 REACTIONS LEANING TOWARD E1 [J].

BUNNETT, JF ;

TANIDA, H ;

DAVIS, GT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (09) :1606-&

[9] KINETICS, PRODUCTS, AND MECHANISM OF REACTION OF TERT-BUTYL CHLORIDE WITH SODIUM ETHANETHIOLATE IN METHANOL AND DIMETHYL-SULFOXIDE METHANOL SOLVENTS - INSIGHT INTO THE OCCASIONAL SUPERIORITY OF THIOLATE OVER ALKOXIDE IONS IN EFFECTING E2 ELIMINATIONS [J].

BUNNETT, JF ;

MIGDAL, CA .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (13) :3041-3045

[10]

BUNNETT JF, 1986, INVESTIGATION RATES, P206

← 1 2 3 →