TICL4/NAI - A NOVEL, EFFICIENT REAGENT FOR MILD REDUCTION OF THE N-O BOND IN AMINE N-OXIDES AND NITRONES

被引：28

作者：

BALICKI, R

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences, Warszawa, PL-01-224

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 03期

关键词：

Titanium; low‐valent / Amine N‐oxides / Deoxygenation;

D O I：

10.1002/cber.19901230336

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heteroaromatic N‐oxides and nitrones were readily and selectively deoxygenated to the corresponding bases or imines in excellent yields with the TiCl4/NaI reagent system. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：647 / 648

页数：2

共 27 条

[1] BALICKI R, 1989, SYNTHESIS-STUTTGART, P645
[2] SELECTIVE REDUCTION OF THE N-O BOND IN HETEROAROMATIC N-OXIDES BY TICL4/SNCL2
BALICKI, R
KACZMAREK, L
MALINOWSKI, M
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (5-6) : 897 - 900
[3] BALICKI R, UNPUB
[4] BAMBERGER E, 1899, BER, V32, P342
[5] BEHRAND R, 1990, LIEBIGS ANN CHEM, V257, P223
[6] BONINI BF, 1979, TETRAHEDRON LETT, P1799
[7] Brady OL, 1926, J CHEM SOC, P2386
[8] DENHERTOG HJ, 1950, RECL TRAV CHIM PAY B, V69, P468
[9] DNSTAN WR, 1899, J CHEM SOC, V75, P792
[10] DEOXYGENATION OF HETEROCYCLIC N-OXIDES .1. NOVEL OXYGEN- AND PEROXIDE-CATALYSED REDUCTION OF PYRIDINE 1-OXIDE WITH TRIETHYL PHOSPHITE
EMERSON, TR
REES, CW
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (MAY): : 1917 - &

← 1 2 3 →