THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A REMARKABLE BINUCLEAR, DOUBLE PD-CL-H-O-PD BRIDGED PALLADIUM ALCOHOL COMPLEX - CATALYTIC OXIDATIONS WITH MOLECULAR-OXYGEN MEDIATED BY [([ME2C(OH)CH2CONME2]PD(CL)NO2)2]

被引：20

作者：

KIERS, NH

FERINGA, BL

KOOIJMAN, H

SPEK, AL

VANLEEUWEN, PWNM

机构：

[1] UNIV GRONINGEN,DEPT ORGAN & MOLEC INORGAN CHEM,NIJENBORGH 16,9747 AG GRONINGEN,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,VAKGRP KRISTAL & STRUKT CHEM,3584 CH UTRECHT,NETHERLANDS

[3] AMSTERDAM SHELL RES BV,KONINKLIJKE SHELL LAB,1003 AA AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pd(Cl)NO2 complex of N,N-3-trimethyl-3-hydroxybutyramide is dimeric in the solid state with two Pd-Cl-H-O-Pd hydrogen-bond bridges; however, in solution the complex is monomeric and catalytically active in the oxidation of alkenes.

引用

页码：1169 / 1170

页数：2

共 19 条

[1] THE TRANSITION-METAL NITRO-NITROSYL REDOX COUPLE - CATALYTIC-OXIDATION OF OLEFINS TO KETONES [J].

ANDREWS, MA ;

KELLY, KP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (10) :2894-2896

[2] SYNTHESIS, CHARACTERIZATION, AND EQUILIBRIA OF PALLADIUM(II) NITRILE, ALKENE, AND HETEROMETALLACYCLOPENTANE COMPLEXES INVOLVED IN METAL NITRO CATALYZED ALKENE OXIDATION REACTIONS [J].

ANDREWS, MA ;

CHANG, TCT ;

CHENG, CWF ;

EMGE, TJ ;

KELLY, KP ;

KOETZLE, TF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) :5913-5920

[3] EPOXIDATION OF CYCLIC ALKENES BY BIS(ACETONITRILE)CHLORONITROPALLADIUM(II) - ON THE ROLE OF HETEROMETALLACYCLOPENTANES AND BETA-HYDROGEN ELIMINATION IN THE CATALYTIC-OXIDATION OF ALKENES [J].

ANDREWS, MA ;

CHENG, CWF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4268-4270

[4] ALCOHOL COMPLEXES OF PLATINUM(II) - SYNTHESES AND CRYSTAL-STRUCTURES OF [S-(R-STAR,R-STAR)]-(+)589-[PT(OSO2CF3)2(1,2-C6H4(PMEPH)2)] AND [S-(R-STAR,R-STAR)]-(+)589-[PT(HOCH2CH2OH)(1,2-C6H4(PMEPH)2)](CF3SO3)2 [J].

APPELT, A ;

ARIARATNAM, V ;

WILLIS, AC ;

WILD, SB .

TETRAHEDRON-ASYMMETRY, 1990, 1 (01) :9-12

[5] HOMOGENEOUS CATALYTIC-OXIDATION OF SECONDARY ALCOHOLS TO KETONES BY MOLECULAR-OXYGEN UNDER MILD CONDITIONS [J].

BLACKBURN, TF ;

SCHWARTZ, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (05) :157-158

[6] The Signer method for determining molecular weights [J].

Clark, EP .

INDUSTRIAL AND ENGINEERING CHEMISTRY-ANALYTICAL EDITION, 1941, 13 :0820-0821

[7] COBALT NITRO COMPLEXES AS OXYGEN-TRANSFER AGENTS .4. EPOXIDATION OF OLEFINS [J].

DIAMOND, SE ;

MARES, F ;

SZALKIEWICZ, A ;

MUCCIGROSSO, DA ;

SOLAR, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4266-4268

[8] OXIDATIVE ADDITION OF PHENOLS TO PD(PCY3)2 - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TRANS-[PD(PCY3)2(H)(OC6H5)].C6H5OH (1) AND TRANS-[PD(PCY3)2(H)(OC6F5)].C6F5OH (2) [J].

DIBUGNO, C ;

PASQUALI, M ;

LEONI, P ;

SABATINO, P ;

BRAGA, D .

INORGANIC CHEMISTRY, 1989, 28 (07) :1390-1394

[9] CATALYTIC-OXIDATION OF ALK-1-ENES TO ALDEHYDES [J].

FERINGA, BL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (12) :909-910

[10]

GAUDEMARBARDONE F, 1979, SYNTHESIS-STUTTGART, P463

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