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SOLUTION CHEMISTRY OF LANTHANIDE MACROCYCLIC COMPLEXES

被引：69
作者：
ARNAUDNEU, F
机构：
来源：
CHEMICAL SOCIETY REVIEWS | 1994年 / 23卷 / 04期
关键词：
D O I：
10.1039/cs9942300235
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this article, the solution chemistry of the interactions between lanthanide cations and macrocyclic receptors is presented through selected examples referring to neutral and ionizable coronands and cryptands as well as phenolic calixarenes and their chemically modified derivatives. The different factors governing the thermodynamics of complexation and the selectivity, e.g. solvent effects, the respective sizes of the cations and the ligands, the number and nature of the binding sites, are discussed.
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页码：235 / 241
页数：7
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