IONIZATION OF LIQUIDS BY RADIATION STUDIED BY METHOD OF PULSE RADIOLYSIS .2. SOLUTIONS OF TRIPHENYLMETHYL CHLORIDE

被引：33

作者：

CAPELLOS, C

ALLEN, AO

机构：

[1] Explosives Laboratory, F. R. L., Dover

[2] Chemistry Department, Brookhaven National Laboratory, Upton

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 10期

关键词：

D O I：

10.1021/j100844a018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solutions of triphenylmethyl chloride in five solvents (n-hexane, cyelohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide) subjected to pulse radiolysis gave yields of triphenylmethyl carbonium ion equal within experimental error to the total yield of free ions in these solvents over the solute concentration range 10-3 to 10-2 M. The ion does not form in the presence of substances like alcohol which possess basic character. Kinetics of formation and decay of the ion were determined.

引用

页码：3264 / &

共 4 条

[1] IONIZATION OF LIQUIDS BY RADIATION STUDIED BY METHOD OF PULSE RADIOLYSIS .I. SOLUTIONS OF N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE IN HYDROCARBONS
CAPELLOS, C
ALLEN, AO
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) : 4265 - &
[2] IONIZATION OF LIQUIDS BY RADIATION - MEASUREMENT BY CHARGE SCAVENGING
CAPELLOS, C
ALLEN, AO
[J]. SCIENCE, 1968, 160 (3825) : 302 - &
[3] YIELD OF FREE IONS IN IRRADIATED LIQUIDS - DETERMINATION BY A CLEARING FIELD
SCHMIDT, WF
ALLEN, AO
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (11) : 3730 - &
[4] PULSE RADIOLYSIS STUDIES .4. SOLVATED ELECTRON IN ALIPHATIC ALCOHOLS
TAUB, IA
HARTER, DA
DORFMAN, LM
SAUER, MC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (04) : 979 - &

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