EXTENDED MEASUREMENT AND ANALYSIS OF THE V3-INFRARED BAND OF METHANE

被引：60

作者：

GRAY, DL ^{[1
]}

ROBIETTE, AG ^{[1
]}

PINE, AS ^{[1
]}

机构：

[1] MIT,LINCOLN LAB,LEXINGTON,MA 02173

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1979年 / 77卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-2852(79)90183-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Previous Doppler-limited measurements of the allowed lines in the ν3 infrared band of 12CH4, recorded using a stabilized difference-frequency tunable infrared laser system, have been extended to P(17), Q(17), and R(19). The data have been analyzed by diagonalization of an effective Hamiltonian for the v3 = 1 state, in which many higher-order terms (including tensor operators of up to eighth rank) have been added to the usual fourth-order expansion. These extra terms are necessary to reproduce the experimental splitting patterns and in particular to fit an unusual inversion of the ordering of the tetrahedral levels for R = J - 1 around J = 14 in the upper state. The standard deviation of the fit to 440 assigned transitions is 0.0056 cm-1, and the calculated intensities are also in good agreement with experiment. © 1979.

引用

页码：440 / 456

页数：17

共 26 条

[1] CALCULATED SEXTIC CENTRIFUGAL-DISTORTION CONSTANTS OF POLYATOMIC-MOLECULES
ALIEV, MR
WATSON, JKG
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 61 (01) : 29 - 52
[2] HIGHER-ORDER ROTATION-VIBRATION ENERGIES OF POLYATOMIC MOLECULES .5.
AMAT, G
NIELSEN, HH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (07) : 1859 - &
[3] EXTENSION OF 106 SAMPLES FOURIER SPECTROMETRY TO INDIUM-ANTIMONIDE REGION - VIBRATION-ROTATION BANDS OF N-14(2)O-16 - 3.3-5.5 MU-M REGION
AMIOT, C
GUELACHVILI, G
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 59 (02) : 171 - 190
[4] MEASUREMENT AND ANALYSIS OF V3 BAND OF METHANE
BARNES, WL
SUSSKIND, J
PLYLER, EK
HUNT, RH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (10) : 5160 - &
[5] NEW ANALYSIS OF UPSILON 3 BAND OF CH-12 4 FROM 2 840 TO 3 167 CM-1
BOBIN, B
FOX, K
[J]. JOURNAL DE PHYSIQUE, 1973, 34 (07): : 571 - 582
[6] HIGH-RESOLUTION FOURIER-TRANSFORM SPECTRUM OF WATER BETWEEN 2930 AND 4255 CM-1
CAMYPEYRET, C
FLAUD, JM
GUELACHVILI, G
AMIOT, C
[J]. MOLECULAR PHYSICS, 1973, 26 (04) : 825 - 855
[7] DANGNHU M, J MOL SPECTROSC, V77, P57
[8] SIMULTANEOUS ANALYSIS OF NU2 AND NU4 BANDS OF METHANE
GRAY, DL
ROBIETTE, AG
[J]. MOLECULAR PHYSICS, 1976, 32 (06) : 1609 - 1625
[9] Guelachvili G., 1972, Nouvelle Revue d'Optique Appliquee, V3, P317, DOI 10.1088/0029-4780/3/6/304
[10] ORBITAL LEVEL SPLITTING IN OCTAHEDRAL SYMMETRY AND SF6 ROTATIONAL SPECTRA .1. QUALITATIVE FEATURES OF HIGH J LEVELS
HARTER, WG
PATTERSON, CW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (11) : 4872 - 4885

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