OXIDATIVE ADDITION AND ISOMERIZATION-REACTIONS - THE STEREOSELECTIVE SYNTHESIS OF CIS-PH2TEX4 AND TRANS-PH2TEX4

被引：12

作者：

JANG, MH

JANZEN, AF

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 52卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80321-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study of the stereoselective synthesis of cis- and trans-Ph2TeX4 (X = F,Cl) supports a two pathway mechanism in which oxidative addition leads to the cis isomer while subsequent isomerization leads to the trans isomer.

引用

页码：45 / 50

页数：6

共 15 条

[1] ORGANOTELLURIUM (VI) FLUORIDES [J].

ALAM, K ;

JANZEN, AF .

JOURNAL OF FLUORINE CHEMISTRY, 1985, 27 (04) :467-469

[2]

Bergman J., 1986, CHEM ORGANIC SELENIU, P517

[3]

BERRY FJ, 1976, J ORGANOMET CHEM, V110, P201, DOI 10.1016/S0022-328X(00)89691-6

[4] FLUORINATION WITH POSITIVE FLUORINE GENERATED FROM ISOELECTRONICALLY RELATED REAGENTS [J].

CARTWRIGHT, M ;

WOOLF, AA .

JOURNAL OF FLUORINE CHEMISTRY, 1981, 19 (02) :101-122

[5]

DESJARDINS CD, 1974, INORG NUCL CHEM LETT, V10, P151

[6] CRYSTAL STRUCTURE OF BETA-DIMETHYLTELLURIUM DI-IODIDE [J].

EINSTEIN, F ;

TROTTER, J ;

WILLISTON, C .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (12) :2018-+

[7] A NEW GEOMETRICAL FORM OF SILICON - SYNTHESIS AND STRUCTURE OF TETRAETHYLAMMONIUM BIS(1,2-BENZENEDIOLATO)FLUOROSILICATE(IV) [J].

HARLAND, JJ ;

DAY, RO ;

VOLLANO, JF ;

SAU, AC ;

HOLMES, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) :5269-5270

[8]

JANZEN AF, 1989, J FLUORINE CHEM, V42, P173

[9]

JANZEN AF, 1988, CAN J CHEM, V66, P1308

[10] ISOMERIZATION, FLUORINE EXCHANGE, AND STEREOSELECTIVE SYNTHESIS OF CIS-F2TEPH3CL AND TRANS-F2TEPH3CL - APPLICATION OF THE COORDINATION MODEL OF REACTION-MECHANISMS [J].

JANZEN, AF ;

JANG, M .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (01) :71-75

← 1 2 →