A NEW FAMILY OF LIGATED ANIONIC INITIATORS FOR THE LIVING POLYMERIZATION OF (METH)ACRYLIC ESTERS

被引：52

作者：

BAYARD, P ^{[1
]}

JEROME, R ^{[1
]}

TEYSSIE, P ^{[1
]}

VARSHNEY, S ^{[1
]}

WANG, JS ^{[1
]}

机构：

[1] UNIV LIEGE,CERM,B6 SART TILMAN,B-4000 LIEGE,BELGIUM

来源：

POLYMER BULLETIN | 1994年 / 32卷 / 04期

关键词：

D O I：

10.1007/BF00587878

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new family of ligands (dual sigma - pi ligand), i.e. chelating lithium alkoxides, Li-O-(CH2-CH2O)nCH3, is shown to be very effective in promoting the living anionic Polymerization of methacrylic and acrylic esters, including a number of primary alkyl acrylates such as n-butyl acrylate and 2-ethylhexylacrylate.

引用

页码：381 / 385

页数：5

共 14 条

[1]

[Anonymous], UNPUB

[2] CONTROLLED POLYMERIZATION OF METHYL-METHACRYLATE USING LITHIUM ALUMINUM ALKYLS [J].