ENANTIOSELECTIVE CATALYTIC BORANE REDUCTIONS OF ACHIRAL KETONES - SYNTHESIS AND APPLICATION OF NEW CHIRAL BETA-AMINO ALCOHOLS FROM L-METHIONINE

被引：12

作者：

MEHLER, T ^{[1
]}

MARTENS, J ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,AMMERLANDER HEERSTR 114-118,D-26129 OLDENBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 09期

关键词：

D O I：

10.1016/S0957-4166(00)82245-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ formed chiral oxazaborolidine catalysts from optically active beta-amino alcohols 1-3 from L-methionine ethyl carboxylate 4 have been used successfully in the enantioselective catalytic homogenous borane reductions of various aromatic ketones. The corresponding optically active alcohols are obtained in high optical purity (up to 100% ee).

引用

页码：1983 / 1986

页数：4

共 33 条

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