STUDIES IN TETRAARYLBORATES .3. PREPARATION AND REAGENT PROPERTIES OF SODIUM TETRAKIS(P-TRIFLUOROMETHYLPHENYL) BORATE AND SODIUM TETRAKIS(M-FLUOROPHENYL) BORATE

被引：35

作者：

VANDEBERG, JT

MOORE, CE

CASSARETO, FP

POSVIC, H

机构：

[1] Department of Chemistry, Loyola University, Chicago

来源：

ANALYTICA CHIMICA ACTA | 1969年 / 44卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0003-2670(01)81750-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Sodium tetrakis(p-trifluoromethylphenyl) borate and sodium tetrakis(m-fluorophenyl) borate were synthesized by a new in situ method. Both salts formed precipitates with potassium, rubidium and cesium ions, quaternary ammonium and protonated basic nitrogen compounds. Potassium tetrakis(p-trifluoromethylphenyl) borate was more insoluble than potassium tetraphenylborate while cesium tetrakis (m-fluorophenyl) borate was less soluble than cesium tetrakis(p-fluorophenyl) borate. The salts formed with nitrogen-containing compounds offer possibilities for qualitative and quantitative analyses. © 1969.

引用

页码：175 / +

页数：1

共 3 条

[1] STUDIES IN TETRAARYLBORATES .I. PREPARATION AND REAGENT PROPERTIES OF SODIUM TETRAKIS(P-CHLOROPHENYL)BORATE
CASSARETTO, FP
MCLAFFER.JJ
MOORE, CE
[J]. ANALYTICA CHIMICA ACTA, 1965, 32 (04) : 376 - +
[2] Gloss G.H., 1953, CHEM ANAL, V42, P50
[3] STUDIES IN TETRAARYLBORATES .2. PREPARATION AND REAGENT PROPERTIES OF SODIUM TETRAKIS(P-FLUOROPHENYL)BORATE A SELECTIVE REAGENT FOR CESIUM
MOORE, CE
CASSARET.FP
POSVIC, H
MCLAFFER.JJ
[J]. ANALYTICA CHIMICA ACTA, 1966, 35 (01) : 1 - &

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