PICOSECOND SATURATION SPECTROSCOPY OF CRESYL VIOLET - ROTATIONAL DIFFUSION BY A STICKING BOUNDARY-CONDITION IN THE LIQUID-PHASE

被引：82

作者：

MILLAR, DP

SHAH, R

ZEWAIL, AH

机构：

[1] Arthur Amos Noyes Laboratory of Chemical Physics4 4 Contribution No. 6053., California Institute of Technology, Pasadena

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)80311-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Picosecond pulses (0.6-2.5 ps duration) from a passively mode-locked and cavity-dumped dye laser have been used to study the molecular reorientation of cresyl violet in liquids. The dipole correlation function is obtained from the decay of the induced dichroism. The results when compared with hydrodynamics give good agreement with the stick boundary condition, and predict effective shape of cresyl violet in the liquid. © 1979.

引用

页码：435 / 440

页数：6

共 26 条

[1] STUDIES IN MOLECULAR DYNAMICS .8. TRANSPORT COEFFICIENTS FOR A HARD-SPHERE FLUID [J].

ALDER, BJ ;

GASS, DM ;

WAINWRIGHT, TE .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (10) :3813-+

[2] MOLECULAR-REORIENTATION IN LIQUIDS - EXPERIMENTAL TEST OF HYDRODYNAMIC MODELS [J].

BAUER, DR ;

BRAUMAN, JI ;

PECORA, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (22) :6840-6843

[3] ULTRASHORT PULSE MEASUREMENTS [J].

BRADLEY, DJ ;

NEW, GHC .

PROCEEDINGS OF THE IEEE, 1974, 62 (03) :313-345

[4] THEORY OF FLUORESCENCE DEPOLARIZATION BY ANISOTROPIC ROTATIONAL DIFFUSION [J].

CHUANG, TJ ;

EISENTHAL, KB .

JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (12) :5094-+

[5]

CHUANG TJ, 1971, CHEM PHYS LETT, V11, P3

[6]

Debye P., 1928, POLAR MOL

[7] STUDIES OF CHEMICAL AND PHYSICAL PROCESSES WITH PICOSECOND LASERS [J].

EISENTHAL, KB .

ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (04) :118-123

[8] DIRECT OBSERVATION OF ROTATIONAL DIFFUSION BY PICOSECOND SPECTROSCOPY [J].

FLEMING, GR ;

MORRIS, JM ;

ROBINSON, GW .

CHEMICAL PHYSICS, 1976, 17 (01) :91-100

[9] SLIP BOUNDARY-CONDITIONS FOR MOLECULAR ROTATION - TIME-DEPENDENT FLUORESCENCE DEPOLARIZATION STUDIES OF BBOT [J].

FLEMING, GR ;

KNIGHT, AEW ;

MORRIS, JM ;

ROBBINS, RJ ;

ROBINSON, GW .

CHEMICAL PHYSICS LETTERS, 1977, 51 (03) :399-402

[10] ROTATIONAL DIFFUSION OF MODE-LOCKING DYE DODCI AND ITS PHOTOISOMER [J].

FLEMING, GR ;

KNIGHT, AEW ;

MORRIS, JM ;

ROBBINS, RJ ;

ROBINSON, GW .

CHEMICAL PHYSICS LETTERS, 1977, 49 (01) :1-7

← 1 2 3 →