HYDROXYCARBOXYLATO OXO-OSMIUM(VI) COMPLEXES

被引：12

作者：

EDWARDS, CF ^{[1
]}

GRIFFITH, WP ^{[1
]}

机构：

[1] IMPERIAL COLL SCI TECHNOL & MED,INORGAN CHEM RES LABS,LONDON SW7 2AY,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83548-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complexes OsO2py2L (L = oxalate, lactate, atrolactate, citrate, quinate), OsO2pic2L (L = oxalate, oxoisobutyrate; pic = 3-methylpyridine), (OsO2py2)2 (tartrate), K2[OsO2L2] (L = glycolate, quinate) and K4[(OsO2)2(tartrate)3] are reported. On the basis of IR, Raman and C-13 NMR studies we believe them to contain trans OsO2 osmyl linkages. X-ray photoelectronic and mass spectral data are also reported for some of them.

引用

页码：61 / 65

页数：5

共 28 条

[1]

ATOVMYAN LO, 1974, J STRUCT CHEM+, V15, P733

[2]

BARBIERI GA, 1916, ATTI ACAD LINCEI REN, V25, P75

[3] COMPLEXES OF W(VI) AND MO(VI) WITH GLYCOLIC, LACTIC, CHLORO-LACTIC AND PHENYL-LACTIC, MANDELIC, AND GLYCERIC ACIDS STUDIED BY H-1 AND C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].

CALDEIRA, MM ;

RAMOS, ML ;

GIL, VMS .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (04) :827-832

[4] COMPLEXES OF MO(VI) WITH LACTIC, THIOLACTIC AND THIOMALIC ACIDS STUDIED BY NMR-SPECTROSCOPY [J].

CALDEIRA, MM ;

GIL, VMS .

POLYHEDRON, 1986, 5 (1-2) :381-385

[5]

CAMPBELL NC, 1984, THESIS U LONDON

[6]

CAMPBELL NC, 1985, INORG CHIM ACTA, V96, pL23

[7] C-13 FOURIER-TRANSFORM NUCLEAR MAGNETIC-RESONANCE STUDY OF GALLIUM CITRATE IN AQUEOUS-SOLUTION [J].

CHANG, CHF ;

PITNER, TP ;

LENKINSKI, RE ;

GLICKSON, JD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :5858-5863

[8]

Criegee R, 1942, LIEBIGS ANN CHEM, V550, P99

[9] X-RAY STRUCTURE OF K4[MO2O2(O2)4(C4H2O6)].4H2O, A NOVEL PEROXO COMPLEX CONTAINING A SINGLE TETRADENTATE BRIDGING TARTRATE [J].

DENGEL, AC ;

GRIFFITH, WP ;

POWELL, RD ;

SKAPSKI, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (07) :555-556

[10] STUDIES ON TRANSITION-METAL PEROXO COMPLEXES .7. MOLYBDENUM(VI) AND TUNGSTEN(VI) CARBOXYLATO PEROXO COMPLEXES, AND THE X-RAY CRYSTAL-STRUCTURE OF K2[MOO(O2)2(GLYC)].2H2O [J].

DENGEL, AC ;

GRIFFITH, WP ;

POWELL, RD ;

SKAPSKI, AC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05) :991-995

← 1 2 3 →