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THE REGIOSPECIFIC AND STEREOSPECIFIC SELECTIVE HYDROGENATION OF ETA-2-COORDINATED ARENES
被引:55
作者
:
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
SCHAEFER, WP
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
SCHAEFER, WP
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
机构
:
[1]
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
[2]
CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,DIV CHEM & CHEM ENGN,PASADENA,CA 91125
来源
:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
|
1990年
/ 112卷
/ 07期
关键词
:
D O I
:
10.1021/ja00163a031
中图分类号
:
O6 [化学];
学科分类号
:
0703 ;
摘要
:
Several η2-bound arene complexes of pentaammineosmium(II) have been selectively hydrogenated to alkene products in the presence of a heterogeneous catalyst (Pd, Rh). In all cases the coordinated osmium was shown both to activate the arene ligand toward catalytic hydrogenation and to protect the alkene product toward further reduction. Hydrogenation can be achieved both regio- and stereoselectivity and is shown to occur exclusively anti to the metal center. The structure of the 3-methoxycyclohexene complex [Os(NH3)5(η2-C7H12O)](OTf)2 has been determined. The hydrogenation of η2-bound anisole or 1,4-dimethoxybenzene is not concerted; the semihydrogenation product, a vinyl ether, rapidly hydrolyzes in acid medium to form a cyclohexenone complex. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:2682 / 2685
页数:4
相关论文
共 12 条
[1]
Augustine R. L., 1965, CATALYTIC HYDROGENAT
[2]
Bard A. J., 2001, ELECTROCHEMICAL METH, V2nd, P50
[3]
DESICCANT EFFICIENCY IN SOLVENT DRYING .3. DIPOLAR APROTIC-SOLVENTS
BURFIELD, DR
论文数:
0
引用数:
0
h-index:
0
BURFIELD, DR
SMITHERS, RH
论文数:
0
引用数:
0
h-index:
0
SMITHERS, RH
[J].
JOURNAL OF ORGANIC CHEMISTRY,
1978,
43
(20)
: 3966
-
3968
[4]
SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF THE (ETA-2-ACETONE)PENTAAMMINEOSMIUM(II) COMPLEX
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
FAIRLIE, DP
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
FAIRLIE, DP
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1986,
108
(26)
: 8223
-
8227
[5]
SUBSTITUENT EFFECTS ON ETA-2-COORDINATED ARENE COMPLEXES OF PENTAAMMINEOSMIUM(II)
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
SEKINE, M
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
SEKINE, M
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1988,
110
(17)
: 5725
-
5731
[6]
SYNTHESIS OF [OS(NH3)5(ETA-2-TMB)]2+ - A VALUABLE PRECURSOR FOR PENTAAMMINEOSMIUM(II) CHEMISTRY
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
INORGANIC CHEMISTRY,
1987,
26
(17)
: 2917
-
2918
[7]
THE SELECTIVE HYDROGENATION OF BENZENE TO CYCLOHEXENE ON PENTAAMMINEOSMIUM(II)
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1988,
110
(23)
: 7906
-
7907
[8]
HARMAN WD, 1987, THESIS STANFORD U
[9]
HARMAN WD, UNPUB
[10]
House H. O., 1972, MODERN SYNTHETIC REA
←
1
2
→
共 12 条
[1]
Augustine R. L., 1965, CATALYTIC HYDROGENAT
[2]
Bard A. J., 2001, ELECTROCHEMICAL METH, V2nd, P50
[3]
DESICCANT EFFICIENCY IN SOLVENT DRYING .3. DIPOLAR APROTIC-SOLVENTS
BURFIELD, DR
论文数:
0
引用数:
0
h-index:
0
BURFIELD, DR
SMITHERS, RH
论文数:
0
引用数:
0
h-index:
0
SMITHERS, RH
[J].
JOURNAL OF ORGANIC CHEMISTRY,
1978,
43
(20)
: 3966
-
3968
[4]
SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF THE (ETA-2-ACETONE)PENTAAMMINEOSMIUM(II) COMPLEX
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
FAIRLIE, DP
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
FAIRLIE, DP
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1986,
108
(26)
: 8223
-
8227
[5]
SUBSTITUENT EFFECTS ON ETA-2-COORDINATED ARENE COMPLEXES OF PENTAAMMINEOSMIUM(II)
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
SEKINE, M
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
SEKINE, M
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1988,
110
(17)
: 5725
-
5731
[6]
SYNTHESIS OF [OS(NH3)5(ETA-2-TMB)]2+ - A VALUABLE PRECURSOR FOR PENTAAMMINEOSMIUM(II) CHEMISTRY
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
INORGANIC CHEMISTRY,
1987,
26
(17)
: 2917
-
2918
[7]
THE SELECTIVE HYDROGENATION OF BENZENE TO CYCLOHEXENE ON PENTAAMMINEOSMIUM(II)
HARMAN, WD
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
HARMAN, WD
TAUBE, H
论文数:
0
引用数:
0
h-index:
0
机构:
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
TAUBE, H
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1988,
110
(23)
: 7906
-
7907
[8]
HARMAN WD, 1987, THESIS STANFORD U
[9]
HARMAN WD, UNPUB
[10]
House H. O., 1972, MODERN SYNTHETIC REA
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1
2
→