A 2PI-X 2SIGMA+ SYSTEM OF BEF

被引:20
作者
WALKER, TEH
BARROW, RF
机构
来源
JOURNAL OF PHYSICS PART B ATOMIC AND MOLECULAR PHYSICS | 1969年 / 2卷 / 01期
关键词
D O I
10.1088/0022-3700/2/1/314
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The A 2π-X 2Σ+ system of BeF has been photographed in absorption at high resolution, and the rotational analysis of the 1-0, 0-0 and 0-1 bands has been completed. The results confirm earlier work that the A 2π state is inverted, although derived mainly from the configuration... σ2π4π. This conclusion is in agreement with recent molecular orbital calculations on BeF, and is to some extent confirmed by other experimental work on this molecule which is briefly discussed.
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页码:102 / &
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