SYNTHESIS OF CEDRENE .1. SYNTHESIS AND STRUCTURE OF A KEY INTERMEDIATE

被引：19

作者：

FETIZON, M ^{[1
]}

LAZARE, S ^{[1
]}

PASCARD, C ^{[1
]}

PRANGE, T ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,CRISTALLOCHIM LAB,F-91190 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 06期

关键词：

D O I：

10.1039/p19790001407

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photocycloaddition of the dienone (5) leads to a major compound (6b) which is an intermediate in a new synthesis of β-cedrene (8). The structure of its crystalline derivative (12b) has been established by X-ray diffraction. In particular, the relative configuration of the 12-methyl and 11-methylene (cedrene numbering) is the correct one.

引用

页码：1407 / 1410

页数：4

共 14 条

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