A RADIOCHEMICAL STUDY OF THE KINETICS OF ION-EXCHANGE ON HYDROUS TITANIUM-DIOXIDE

被引:16
作者
ELNAGGAR, IM [1 ]
ELABSY, MA [1 ]
机构
[1] ATOM ENERGY ESTAB,DEPT RADIOISOTOPE PROD & LABELLED CPDS,CAIRO,EGYPT
来源
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1992年 / 157卷 / 02期
关键词
D O I
10.1007/BF02047446
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports a radiochemical study of the kinetics of ion exchange of Na+ and Cs+ with H+ on hydrous titanium dioxide. The experimental conditions are set to favor the particle diffusion mechanism only, and this is confirmed by the Bt versus t plots. On the basis of these studies the various physical parameters such as the effective diffusion coefficients, activation energies and entropies of activation have been evaluated. Tentative explanations are given for these results, from which some conclusions are drawn.
引用
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页码:313 / 320
页数:8
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