SYNTHESIS OF BENZO[G]CHRYSENE 5,6-OXIDE AND 7,8-OXIDE AND THEIR ISOMERIC OXEPINES

被引：4

作者：

AGARWAL, R ^{[1
]}

BOYD, DR ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 23期

关键词：

D O I：

10.1039/p19930002869

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzo[g]chrysene 5,6-oxide and benzo[g]chrysene 7,8-oxide when synthesised from dibromo acetate precursors were accompanied by the stable oxepine isomers benzo[3,4]phenanthro[2,1-b]oxepine and benzo[3,4]phenanthro[1,2-b]oxepine. The isolation of the latter oxepines, and their formation by photochemichal rearrangement of the isomeric arene oxides, are in accord with earlier predictions from PMO calculations.

引用

页码：2869 / 2874

页数：6

共 17 条

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