SPECTROSCOPIC CHARACTERIZATION OF ELECTROPHILIC D4 METHYLENE AND BENZYLIDENE COMPLEXES OF THE TYPE CP(CO)2(L)M=CHR+ (L = PPH3, PET3 - M = MO, W - R = H, PH) - EXPERIMENTAL-DETERMINATION OF BARRIERS TO ROTATION ABOUT THE TUNGSTEN-METHYLENE MULTIPLE BOND

被引：84

作者：

KEGLEY, SE

BROOKHART, M

HUSK, GR

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27514

[2] USA,RES OFF,RES TRIANGLE PK,NC 27709

来源：

ORGANOMETALLICS | 1982年 / 1卷 / 05期

关键词：

D O I：

10.1021/om00065a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：760 / 762

页数：3

共 29 条

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[4] MEASUREMENT OF BARRIERS TO ARYL ROTATION IN CP(CO)2FE=CHC6H5+ AND CP(CO)2FE=CH(P-CH3C6H4)+
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) : 7802 - 7803
[6] SPECTROSCOPIC CHARACTERIZATION OF AN ELECTROPHILIC TRANSITION-METAL-METHYLENE COMPLEX, ETA5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]FE=CH2+
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[7] FACILE SYNTHESIS, SPECTRAL CHARACTERIZATION, AND ETHYLIDENE TRANSFER-REACTIONS OF COMPLEXES OF THE TYPE CP(CO)(L)FE=CHCH3+
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) : 979 - 981
[8] ISOLATION OF STABLE SECONDARY CATIONIC IRON CARBENE COMPLEXES ETA-5-C5H5(CO)2FECHC6H5PF6 AND "ETA-5-C5H5(CO)[P(C6H5)3]FECHC6H5PF6
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NELSON, GO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) : 6099 - 6101
[9] CAULTON KG, 1981, J AM CHEM SOC, V103, P5596
[10] CETINKAYA B, 1973, J CHEM SOC DALTON, P906

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